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Hippokrates Ueber die Krankheiten III
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A b-diketiminato n-butylmagnesium complex is presented as a selective precatalyst for the reductive hydroboration of organic nitriles with pinacolborane (HBpin). Stoichiometric reactivity studies indicate that catalytic turnover ensues through the generation of magnesium aldimido, aldimidoborate and borylamido intermediates, which are formed in a sequence of intramolecular nitrile insertion and...
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ژورنال
عنوان ژورنال: Berichte der deutschen chemischen Gesellschaft
سال: 1906
ISSN: 0365-9496,1099-0682
DOI: 10.1002/cber.190603901154